Lets get started with using Zoho Business! Its a simple process from creating your account to, setting up an organization and adding users. The flow chart given below describes pictorially how to get started with using Zoho Business...
Getting Started-Zoho Business Deployment Guide :

Zoho Business Personal User:
You can use Zoho Business for your personal use as a single user only, in which case after you create your account, you can access various applications, add apps, etc..
As a business user, after signing up:
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Create an organization for your members, create portal URL, have a personal company logo.
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Once you create an organization you can define policies for your members, create groups, assign tasks, share events and docs, etc
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Add or register for a domain and receive your domain-based emails
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If you are registering for a domain, MX Records are configured automatically, add/import users, add mail domains, add the mail aliases and receive domain based emails.
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For domain added to Zoho, after validating it, add users, add mail domains, add mail aliases, configure your MX Records and receive domain based emails.